• Graphical abstract: Inorganic-organic hybrid materials constructed from [(VO2)(HPO4)] helical chains and [M(4,4'-bpy)2]2+ (M = Co, Ni) fragments

  • Figure 2. View of the structure of 1 and 2 along the (101)plane,showing the channels.

论文摘要

Both left-handed and right-handed helical chains of [(VO2)(HPO4)], which are linked by [M(4,4′-bpy)2] to form three-dimensional framework structures (see picture), are present in the structures of two novel inorganic–organic hybrid materials, [M(4,4′-bpy)2(VO2)2(HPO4)4]. These were prepared from hydrothermal systems and characterized by single-crystal X-ray diffraction. M=Co or Ni; bpy=bipyridine.

论文题目

Inorganic-organic hybrid materials constructed from [(VO2)(HPO4)] helical chains and [M(4,4'-bpy)2]2+ (M = Co, Ni) fragments

发表刊物
Angew.Chem.,Int.Ed.,2000,39(13),2325-2327.Z.Shi, S.Feng*, S.Gao, L.Zhang, G.Yang, J.Hua